胶黏物模型物在抄造系统中的稳定特性研究
耿胜芳1 李 擘1，2,* 唐亚男1 王志伟3 武书彬1
（1.华南理工大学制浆造纸工程国家重点实验室，广东广州，510641；
2.江苏省制浆
造纸科学与技术重点实验室（南京林业大学），江苏南京，210037；
3.广西大学轻工与
食品工程学院，广西清洁化制浆造纸与污染控制重点实验室，广西南宁，530004）
摘 要：选取造纸常用的施胶剂烷基烯酮二聚体（AKD）和涂布胶黏剂羧基丁苯胶乳（XSBRL）作为抄造白水微细胶黏物模型物，就其在液相中的稳定特性进行研究分析。采用红外光谱（FTIR）、扫描电镜（SEM）对AKD和XSBRL进行表征，通过示差扫描量热法（DSC）和热重法（TG）对其热性能进行分析，运用激光探测技术、流式技术以及荧光示踪技术相结合的方法，就抄造系统的有关参数对模型物粒径分布的影响进行研究。结果表明，相对于常温时的玻璃态，两种模型物在抄造系统常见温度范围内均处于发黏、高弹态，颗粒间发生聚集，其中，XSBRL对温度更为敏感，聚集程度比AKD的要高，并且随着系统温度的升高，两模型物的聚集趋势都略有上升；当系统温度保持在50℃时，两模型物的聚集状态都随时间延续略有增加，但随时间延续，变化幅度不大；机械搅拌作用的影响与其作用的强度有关，搅拌速度高于800 r/min时，两模型物颗粒间由轻微的聚集趋势转变为分散趋势。
关键词：微细胶黏物；模型物；稳定特性
中图分类号：TS7
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.001
Study of the Stability Characteristics of the Stickies Model Compounds in Papermaking System
GENG Shengfang1 LI Bo1,2,* TANG Yanan1 WANG Zhiwei3 WU Shubin1
(1. Stake Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510641;
2. Jiangsu Provincial Key Lab of Pulp and Paper Science and Technology, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037;
3. Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control, College of Light Industry and Food Engineering,
Guangxi University, Nanning, Guangxi Zhuang Autonomous Region, 530004)
(*Email: ppboli@scut.edu.cn)
Abstract：The common sizing agent, alkylketene dimer (AKD), and the coating binder carboxylated styrenebutadiene latex (XSBRL), were taken as model compounds of microstickies in whitewater to investigate their stability characteristics in the liquid phase. The basic characteristics of AKD and XSBRL were characterized by Infrared Spectrometric Analyzer (FTIR) and Scanning Electron Microscopy (SEM), and the thermal properties were analyzed through differential scanning calorimetry (DSC) and thermogravimetry (TG). Furthermore, the effects of the conditions of papermaking system on the change of the particle size distribution were investigated by using a method combining laser, flow cytometric technology and fluorescent tracers. The results showed that both of the two model compounds were sticky and in high elastic state in the temperature range of papermaking system compared with in glass state at room temperature, which induced the aggregation among particles. XSBRL was more sensitive to temperature and its aggregation degree was higher than AKDs. With the temperature increasing, the aggregation tendencies of these two model compounds were slightly increased. When the system temperature was kept at 50℃, the aggregation state of the two model compounds increased slightly and changed marginally with time went on. The effect of mechanical agitation on
the particle size distribution of the two model compounds was related to the strength of agitation. The particles of the two model compounds didnt slightly aggregate anymore and tended to disperse when the stirring speed exceeded 600~800 r/min.
Key words：microstickies; model compounds; stability characteristics
细菌纤维素絮凝材料制备及其
处理造纸废水性能研究
孙映宏1 王逸锋1 谈学松2 陈艳霞2 熊彩霞2 张 勇2，*
（1.杭州市水文水资源监测总站，浙江杭州，310016；
2.浙江理工大学材料与纺织学院，浙江杭州，310018）
摘 要：以醋酸杆菌构建分泌细菌纤维素（Bacterial Cellulose， BC）的菌种体系，通过优化发酵培养工艺和化学改性条件，制备BC絮凝材料。再通过优化混凝工艺，评价其对造纸废水的混凝处理能力。结果表明，制备的BC絮凝材料具有良好的三维网状结构，其羧基含量显著增加。通过Zeta电位检测表明该BC絮凝材料为阴离子型；且该材料对造纸废水平均浊度去除率可达94.6%，具有优良的混凝沉淀能力。
关键词：细菌纤维素；絮凝材料；化学改性；造纸废水；混凝性能
中图分类号：X793
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.002
Preparation of Bacterial Cellulose Flocculant and Its Flocculation Performance in Papermaking Wastewater
SUN Yinghong1 WANG Yifeng1 TAN Xuesong2 CHEN Yanxia2
XIONG Caixia2 ZHANG Yong2,*
(1. Hydrology and Water Resources Monitoring Station in Hangzhou, Hangzhou, Zhejiang Province, 310016;
2. College of Material and Textile, Zhejiang SciTech University, Hangzhou, Zhejiang Province, 310018)
(*Email: zhangyong@zstu.edu.cn)
Abstract：In this work, the bacteria system for preparing bacterial cellulose (BC) was constructed by using acetobacter. The threedimensional network BC was produced through optimizing its fermentation process. The BC green flocculant was prepared by further chemical modification on BC and its flocculation performance in papermaking wastewater was also evaluated. The positived results showed that the obtained BC held typical threedimensional network structure. The carboxyl content of the BC green flocculant product increased significantly.It belonged to anionic flocculant based on Zeta potential test. The results of papermaking wastewater flocculation indicated that the BC flocculant had excellent flocculation ability and its turbidity removal rate reached 94.6%.
Key words：bacterial cellulose; flocculant material; chemical modification; papermaking wastewater; flocculantion performance
机械木浆纤维形变性表征及其
对纤维间结合性能的影响
王 欣1 李志强1 张红杰1，2，3,* 钱学君2 程洪顺2 张凤山3 李晓亮3
（1.天津科技大学天津市制浆造纸重点实验室，天津，300457；
2.河北华泰纸业有限公司，
河北赵县，051530；
3.山东华泰纸业股份有限公司，山东东营，257335）
摘 要：针对不同木素含量的纤维原料，采用不同评价方法对其形变性能进行表征，包括纤维柔软性（F）、纤维横截面纵横比（AR）和纤维压溃指数（CI）；同时围绕纤维形变性对纤维间结合性能以及手抄片物理强度的影响进行分析。结果表明，F、AR和CI都可以用来表征纤维的形变性，其中，当木素含量从24.28%减少到2.67%时，F表征的相对形变量为956.5%，数倍于其他两者，说明F这一指标表征的更为全面；随着F从0.516×1012 N-1·m-2增加到5.454×1012 N-1·m-2，纸张中纤维间的相对结合面积（RBA）和剪切结合强度（b）增大，Page结合强度指数从3.60 N·m/g线性增加到84.07 N·m/g；在纸张成形过程中，可以通过改变纤维形变性能调节纸张强度和松厚度之间的对立关系。
关键词：木浆纤维；形变性；结合性能；柔软性
中图分类号：TS71.2
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.003
The Characterization of Deformation Behavior of Mechanical Lignocellulosic Fibers and
Its Effect on Interfiber Bonding Properties
WANG Xin1 LI Zhiqiang1 ZHANG Hongjie1,2,3,* QIAN Xuejun2
CHENG Hongshun2 ZHANG Fengshan3 LI Xiaoliang3
(1. Tianjin Key Lab of Pulp & Paper, Tianjin University of Science & Technology, Tianjin, 300457;
2. Hebei Huatai Paper Industry
Co., Ltd., Zhaoxian, Hebei Province, 051530;
3. Shandong Huatai Paper Industry Co., Ltd., Dongying, Shandong Province, 257335)
(*Email: hongjiezhang@tust.edu.cn)
Abstract：In this study, the pine TMP was delignified with sodium chlorite under acidic conditions, to obtain pulp fibers with different lignin contents. The deformation properties of these fibers were characterized by different methods, including flexibility of fiber(F), aspect ratio of fiber cross section(AR) and deformation index of fiber(CI). Finally, the effects of fiber deformation behavior on the interfiber bonding properties and physical strength of handsheets were discussed in details. The results showed that the F, AR and CI could characterize the fiber deformation, when the lignin content decreased from 24.28% to 2.67%, the change of relative deformation characterized by F was 956.5%, which was several times greater than that characterized by the others, therefore, F was the most comprehensive characterization index among them; the increase of F from 0.516×1012 N-1·m-2 to 5.454×1012 N-1·m-2 contributed to the increase of the relative bonding area (RBA) and shear bond strength (b) of the fibers, which led to the linear increase of the Page bonding strength index from 3.60 N·m/g to 84.07 N·m/g. During the paper sheet forming process, the contradiction relationship between physical strength and bulk properties of the paper sheets could be alleviated by adjusting the deformation properties of fiber materials.
Key words：lignocellulosic fiber; deformation property; bonding property;flexibility
C3HRNAi转基因杨木木质部
纤维形态特征研究
苏明垒1，2 刘苍伟1 王玉荣1，2，* 孙海燕1，2
（1.中国林业科学研究院木材工业研究所，北京，100091；
2.中国林业科学研究院林业新技术研究所，北京，100091）
摘 要：为了探明基因调控对杨树木质部纤维形态的影响，采用切片制作结合光学和电子显微镜以及纤维离析的方法，观测了不同高度的C3HRNAi转基因杨木及其对照组杨木的纤维形态特征及参数。结果表明，转基因杨木上、中、下3部位的纤维壁厚值分别较对照组的下降了13.16%、13.47%和10.71%，而腔径值无明显差异，上、中、下3部位的纤维长度和长宽比分别较对照组的上升了1.39%、8.52%、3.80%和9.48%、16.24%、8.97%，纤维宽度分别下降了7.40%、6.64%、4.72%。发现转基因杨木和对照组杨木纤维壁厚和长度等纤维形态参数值均随木质化程度的增加而增加，并且中、下部位纤维形态更适用于制浆造纸。
关键词：C3H基因；杨木；纤维形态；微观结构
中图分类号：TS721+.1
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.004
Study on Fiber Morphological Characteristics of the
C3HRNAi Transgenic Poplars
SU Minglei1,2 LIU Cangwei1 WANG Yurong1,2,* SUN Haiyan1,2
（1. Research Institute of Wood Industry， Chinese Academy of Forestry， Beijing， 100091；
2. Research Institute of Forestry New Technology， Chinese Academy of Forestry， Beijing， 100091）
（*Email：yurwang@caf.ac.cn）
Abstract：In this paper, C3H downregulated transgenic poplar and nontransgenic poplar were selected as materials to study the effect of gene regulation on the morphology of xylem fibers. The morphological characteristics and parameters of xylem fibers at different height of two kinds of poplar were observed from the sections and the isolated fibers by means of light and electronic microscopes. The results showed that the fiber cell walls thickness of the upper, middle and lower part of transgenic poplar decreased by 13.16%, 13.47% and 10.71%, compared with that of the control group respectively, but there was no significant difference in lumen diameter.Fiber length and length /width ratio increased by 1.39%, 8.52%, 3.80% and 9.48%，16.24%，8.97% respectively, and the fiber width decreased by 7.40%, 6.64%, 4.72% respectively. It was also found that fiber morphological parameters such as wall thickness and fiber length of two kinds poplar increased with the lignification degree increasing, and the fiber morphologies of the middle and lower parts were more favorable for paper making. The results showed that the change of C3H gene activity improved the fiber morphology of poplar and made it more suitable for pulp wood utilization.
Key words：C3H; poplar; fiber morphology; microstructure
洗漂过程对棉浆黏度影响因素的研究
邹 杨 吴广文* 胡争朋 熊 奇 熊 泽
（武汉工程大学新型反应器与绿色化工重点实验室，湖北武汉，430073）
摘 要：以蒸煮后棉浆为研究对象，通过正交实验确定最佳洗涤参数，探讨了在该洗涤条件下残氯、Ca2+、Na+浓度对棉浆黏度的影响，并采用R5法自制ClO2漂液，进一步分析漂白阶段漂液浓度对棉浆黏度的影响。结果表明，洗涤中各参数对棉浆黏度影响的顺序为：残氯浓度＞Ca2+＞洗涤时间＞pH值。在残氯浓度为0.036 g/L，Ca2+浓度为90 mg/L，洗涤时间为1 h，pH值为7时洗涤最佳。通过改变洗涤参数中残氯浓度，发现随着残氯的增加，棉浆黏度的下降率呈先下降后上升趋势，其下降率的最小值为11%；同时，调整Ca2+浓度，发现在Ca2+为110 mg/L时棉浆黏度下降率最低。另外，洗涤过程中添加NaCl，可使棉浆黏度下降率达2.2%；改变漂白阶段漂液浓度，使得棉浆黏度下降率为2.1%。
关键词：水洗；漂白；黏度；二氧化氯
中图分类号：TQ340.8;TQ340.6
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.005
An Experimental Research on Factors That Influence Viscosity of Refined
Cotton Solution During Rinsing Process
ZOU Yang WU Guangwen* HU Zhengpeng XIONG Qi XIONG Ze
(Key Lab of Novel Reactor and Green Chemical Engineering of Wuhan Insituce of Technology, Wuhan, Hubei Province, 430073)
(*Email: wuguangwen028@163.com)
Abstract：In this paper, cotton pulp as the research object, the best washing paramenters were determoned by orthogonal test. The effects of residual chlorine, Ca2+, and Na+ concentration on the viscosity in highquality water,
were discussed during washing process. ClO2 bleaching liquid was made through R5. And the effect of its concentration on the viscosity was studied during bleaching process. The results showed that the order of four factors influenced the viscosity in different degrees: residual chlorine>Ca2+>residence time>pH. When the residual chlorine concentration was 0.036 g/L, the Ca2+concentration 90 mg/L, the residence time 1 h and the pH 7, the highquality water of washing could be achieved. When residual chlorine concentration in highquality water was changed, viscosity decent rate had intended to increase after decreasing with the increase of residual chlorine, and the minimum rate was 11%. When Ca2+ concentration was altered, it was discovered that the minimum rate could be realized with Ca2+ concentration being 110 mg/L. When NaCl was added to the highquality water, the rate could be 2.2%. When bleaching liquid purity was changed in bleaching process, the rate could only be 2.1%.
Key words：washing; bleach; viscosity; ClO2
沙蒿胶、瓜尔豆胶对纸质文物
加固的初步研究
吴依茜 张建全 俄 军 弥卓君 赵亚军 陈庚龄
（甘肃省博物馆文物保护研究中心，甘肃兰州，730050）
摘 要：采用自制的沙蒿胶（Artemisia sphaerocephala gum，ASG）、瓜尔豆胶（Guar gum，GG）及二者混合物对纸张表面进行喷涂加固处理。考察了不同喷涂处理条件对生宣纸（纸质文物修复专用手抄纸）老化前后抗张强度、耐折度和光泽度的影响，并用扫描电子显微镜（SEM）进行纸张表面形貌表征。结果表明，ASG质量分数为0.4%、GG质量分数0.2%时对生宣纸有较好的加固效果；GG和ASG以6∶4的配比混合后，GGASG混合物对生宣纸的抗张强度和耐折度有明显的增强作用，对生宣纸光泽度无明显的影响；SEM分析证实了GGASG混合物对生宣纸纤维起到了保护和桥梁作用，有效地改善了生宣纸抗老化能力，酸老化后生宣纸抗张强度损失4.45%，耐折度损失1.76%。
关键词：多糖；沙蒿胶；瓜尔豆胶；纸质文物；加固
中图分类号：TS761
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.006
Preliminary Study on the Protection and Reinforcement of Paper Relic by
Artemisia Sphaerocephala Gum and Guar Gum
WU Yiqian* ZHANG Jianquan E Jun MI Zhuojun ZHAO Yajun CHEN Gengling
(Gansu Museum, Lanzhou, Gansu Province, 730050)
(*Email: wyq127127@126.com)
Abstract：Polysaccharide is a kind of natural polymer which is abundant in natural sources and environment friendly. In this paper, in order to study the protection effectiveness of Artemisia sphaerocephala gum (ASG), guar gum (GG) and the mixtures to the ancient paper based relics, the tensile strength, folding endurance and gloss of the samples after treatment by different concentration of ASG and GG were tested. Moreover, scanning electron microscope (SEM) was used to observe and analyze the surface morphology of the samples. It was found that ASG (0.4 wt%) and GG (0.2 wt%)exhibited enhancing effect on treatedpaper historic relic. Moreover, results showed that samples treated with GGASG mixture(6∶4) not only maintained the original texture, gloss, but also significantly increased the tensile strength and folding endurance. SEM confirmed that the GGASG mixture played a protective and connective role in the paper fibers. Tensile strength only decreased by 4.41% and folding endurance decreased by 1.76% after aging. It indicated that ASG, GG and their mixture showed positive effect on the protection of paper historic relic.
Key words：polysaccharide; Artemisia sphaerocephala gum; guar gum; paper historical relics; reinforcement
不同溶剂预处理对烟梗打浆抄造
及评吸性能的影响
侯 轶1，2 张凌涛1 胡亚成1 李友明1，* 戴 亚2
（1.华南理工大学制浆造纸工程国家重点实验室，广东广州，510640；
2.重庆中烟工业有限责任公司，重庆，400060）
摘 要：以热水抽提、乙醇水溶液和碱性离子液体1，3二甲基咪唑磷酸二甲酯（［MMIM］DMP）为溶剂，对烟梗进行预处理，研究不同溶剂对烟梗中木素的去除效果及溶剂处理后打浆抄造性能和再造烟叶评吸性能的变化。结果表明，碱性离子液体对烟梗中木素的去除率最高，约为热水抽提的5倍，远大于乙醇水溶液对木素的去除率；相对于热水抽提和乙醇水溶液处理，经碱性离子液体处理后的烟梗打浆后纤维的分散程度较好，打浆性能明显提升，抗张强度提高，松厚度和透气度也得到了进一步改善；碱性离子液体脱除烟梗中大量木素后，使各烟气指标的含量和感官质量指标的分数得到了优化，评吸性能明显改善，从而提高了烟草废弃物的利用率，提升了再造烟叶产品品质。
关键词：烟梗；木素；打浆抄造性能；评吸性能
中图分类号：TS424
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.007
Effects of Tobacco Stem Treated with Different Solvention Its Beating Sheet Forming
and Smoking Performance
HOU Yi1，2 ZHANG Lingtao1 HU Yacheng1 LI Youming1,* DAI Ya2
(1. State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640;
2. Chongqing Tobacco Industry Co., Ltd., Chongqing, 400060)
(*Email: ymli3@scut.edu.cn)
Abstract：This paper studied beating performance, sheet forming performance of tobacco stem(a kind of reconstituted tobacco raw material)which was extracted with water, ethanol water solution and alkaline ionic liquid ［MMIM］DMP and the smoking performance of the reconstituted tobacco sheet. The results showed that the removal rate of lignin in tobacco stems extracted by ［MMIM］DMP was the highest, which was about 5 times of that extracted by water and even much higher than ethanol aqueous solution. Compared with the water and ethanol aqueous solution, the beating and sheet forming performances of tobacco stem extracted with ［MMIM］DMP were upgraded significantly the tensile strength and bulk as well as permeability of the treated sheet were improved. After the massive delignification in tobacco stem extracted by ［MMIM］DMP, the contents of the smoke compositions and the scores of the sensory quality index were optimized, and the smoking performance was improved obviously, which improved the quality of the reconstituted tobacco product.
Key words：tobacco stems; lignin; beating and papermaking performance; smoking performance
竹纤维真空绝热板芯材的
结构和性能研究
董 旭 戴达松 范毜仔 赵伟刚 李玉歧 赵 鹤
吴 慧 黄六莲 陈礼辉*
（福建农林大学材料工程学院，福建福州，350108）
摘 要：以漂白竹浆为原料，探讨了打浆度对竹纤维真空绝热板芯材结构和性能的影响，以期获得隔热性能较好的竹纤维真空绝热板。结果表明，在打浆度为14.9°SR条件下，竹纤维真空绝热板芯材的平均孔径为21.7 μm，孔隙率为75.7%，密度为0.287 g/cm3；由其制备出的竹纤维真空绝热板导热系数为12.6 mW/（m·K），具有较好的隔热性能。通过扫描电子显微镜和透气度测定仪分析表明，随着打浆度的增加，竹纤维真空绝热板芯材纤维表面分丝帚化严重，结构致密，透气性能降低。
关键词：竹纤维；打浆度；孔隙率；导热系数
中图分类号：TS761
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.008
Structure and Property of the Vacuum Core Material of Insulation Panel Made of the Bamboo Fibers
DONG Xu DAI Dasong FAN Mizi ZHAO Weigang LI Yuqi
ZHAO He WU hui HUANG Liulian CHEN Lihui*
（College of Material and Engineering, Fujian Agriculture and Forest University, Fuzhou, Fujian Province, 350108）
(*Email: FAFUCLH@163.com)
Abstract：The effects of beating degree on of bamboo fibers the structure and property of the core material of vacuum insulation panel made of bamboo fibers were studied in order to obtain the better insulation performance of the vacuum insulation panel. The results showed that the average pore diameter porosity and density of the core material of vacuum insulation panel were 21.7 μm， 75.7% and 0.287 g/cm3 respectively when beating degree of the bamboo fibers was 14.9°SR, thermal conductivity of the vacuum insulation panel was 12.6 mW/(m·k)which load better insulation performance. SEM observation and air permeability testing results showed that the core material became more compact with lower air permeability as further fibrillation of the fibers with increasing of beating degree.
Key words：bamboo fiber； beating degree； porosity； thermal conductivity
聚乙烯亚胺改性硅藻土的制备与表征
尚 尉1，2 于海辉1 张晓君1
（1.东北电力大学化学工程学院，吉林吉林，132012；
2.东北林业大学生物质材料科学与技术教育部重点实验室，黑龙江哈尔滨，150040）
摘 要：采用聚乙烯亚胺（PEI）和十二烷基磺酸钠（SDS），通过浸渍法对硅藻土进行表面改性，研究了硅藻土对PEI的吸附，硅藻土改性后Zeta电位、粒径和形貌特征的变化，以及纸浆中添加改性硅藻土对浆料Zeta电位和滤水性的影响。研究结果表明，PEI能够对硅藻土进行有效改性，与硅藻土相比，PEI改性硅藻土颗粒表面Zeta电位由负电性转变为正电性，粒径增加，当PEI平衡吸附浓度为0.24 mg/mL时，硅藻土颗粒Zeta电位和粒径分别为25.03 mV和14.05 μm。PEI改性硅藻土作为造纸填料，可有效提高浆料Zeta电位，并改善浆料滤水性能。
关键词：聚乙烯亚胺；硅藻土；填料；表征
中图分类号：TS727
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.009
Preparation and Characterization of Polyethy Leneimine Modified Diatomite
SHANG Wei1,2,* YU Haihui1 ZHANG Xiaojun1
(1. College of Chemistry Engineering, Northeast Electric Power University, Jilin, Jilin Province, 132012；
2. Key Lab of Biobased Material Science and Technology of Ministry of Education, Material Science and Engineering College,
Northeast Forestry University, Harbin, Heilongjiang Province, 150040)
(*Email: sud@163.com)
Abstract：Using polyethyleneimine（PEI）and sodium dodecyl sulfate as modifiers, the surface of diatomite particles was modified by impregnation method. The adsorption of diatomite to PEI was investigated. The morphology, particle size, and Zeta potential of the PEI modified diatomite filler were also determined. The influences of modified diatomite filler on filler retention, Zeta potential and drainability of furnish were studied. The results indicated that PEI was effective to modified diatomite.Compared with the unmodified diatomite, Zeta potential of the modified diatomite was changed from electronegative to electropositive.Particle size was also increased. The Zeta potential and particle size of the diatomite particles were 25.03 mV and 14.05 μm, when the equilibrium adsorption concentration of the PEI was 0.24 mg/mL. PEI modified diatomite filler can effectively improve the Zeta potential of the pulp. The filtering performance of pulp was effectively improved.
Key words：polyethyleneimine； diatomite； filler； characterization
基于自适应神经模糊推理系统的
纸病二次辨识
王亚波1 周 强1,* 王伟刚1 王 莹2
（1.陕西科技大学电气与信息工程学院，陕西西安，710021;
2.陕西科技大学材料科学与工程学院，陕西西安，710021）
摘 要：针对造纸生产线上宽幅高速纸机纸病检测系统快速性和精确性的挑战，提出“工业相机+FPGA（FieldProgrammable Gate Array）+计算机”模式下的基于自适应神经模糊推理系统的纸病二次辨识方法。使用CCD相机采集纸张图像，通过FPGA完成图像预处理和一次辨识（粗辨识+过辨识）；计算机通过自适应神经模糊推理系统（ANFIS）对疑似纸病区域二次辨识（精确辨识），判断出纸病和种类。实验表明，该方法能够准确地辨识各种纸病。
关键词：机器视觉；FPGA；纸病二次辨识；自适应神经模糊推理系统（ANFIS）
中图分类号：TS736
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.010
The Secondary Identification of Paper Defects Based on Adaptive Neuralfuzzy Inference System
WANG Yabo1 ZHOU Qiang1,* WANG Weigang1 WANG Ying2
(1. College of Electrical and Information Engineering, Shaanxi University of Science & Technology, Xian, Shaanxi Province, 710021;
2. Material Science and Engineering Institute, Shaanxi University of Science & Technology, Xian, Shaanxi Province, 710021)
(*Email: zhouqiang@sust.edu.cn)
Abstract：In order to ensure the contradiction between the speed and accuracy in paper defects detection on the wide and high speed paper machine, a method of paper defects secondary identification was put forward based on adaptive neuralfuzzy inference system (ANFIS) on the mode of “FPGA+computer”. The paper images collected by CCD cameras were completed image preprocessing and the first identification through FPGA; by using the ANFIS, the computer was able to complete the second identification of the suspected paper defects area to determine whether the paper defects existed and its type. Experiments showed that the method could accurately identify various paper defects.
Key words：machine vision; FPGA; secondary identification of paper disease; adaptive neuralfuzzy inference system (ANFIS)
宽幅纸机液压刮刀摆动器的
设计与开发
李若冰
（廊坊燕京职业技术学院机电工程系，河北廊坊，065200）
摘 要：液压刮刀摆动器由于不采用电气元件，体积小而输出力大，防水效果良好，高温环境下亦能稳定运行，广泛适用于纸机湿部潮湿的环境以及烘干部高温环境。在宽幅纸机中，液压刮刀摆动器工作效率高，能降低纸机的能耗，减小吨纸的耗电量，具有明显的节能效果。
关键词：液压刮刀摆动器；防水；节能
中图分类号：TS734+.8
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.011
Development of Hydraulic Doctor Oscillator Used in Wide Paper Machine
LI Ruobing
(Department of Electromachinery Engineering， Langfang Yanjing Vocational and Technical College， Langfang， Hebei Province， 065200)
(Email: 79390244@qq.com)
Abstract：Traditionally the doctor oscillators in paper machine are electromechanical oscillator and pneumatic oscillator, but this two kinds are not suitable for wetend section due to humid environment. A new kind of hydraulic oscillator was designed, it was small but had a much bigger output force without any electronic device, it also had very good water proof performance to assure a long life time, which contributed to energy saving for the paper mill.
Key words：hydraulic doctor oscillator； water proof； energy saving
环境规制对我国造纸行业
绿色技术创新的影响研究
许 华 刘佳华*
（陕西科技大学经济与管理学院，陕西西安，710021）
摘 要：首先分析在当今社会环境规制下造纸行业的污染现状；其次选取工业三废的5个指标对我国造纸行业环境规制强度进行测算，通过选取7个绿色技术创新指标运用灰色关联度法进行实证分析。结果表明，环境规制强度与新产品开发经费支出关联度最大，与R&D经费内部支出关联度最小，介于二者之间关联度从小到大依次为新产品销售收入、新产品开发项目数、专利申请数和R&D人员。根据分析结果，对环境规制下我国造纸行业绿色发展提出相应的对策。
关键词：环境规制；造纸行业；绿色技术创新；对策研究
中图分类号：F732
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.012
Study on the Influence of Environmental Regulations on Green Technology
Innovation in Chinas Paper Industry
XU Hua LIU Jiahua*
（School of Economics and Management, Shaanxi University of Science & Technology, Xian, Shaanxi Province, 710021）
（*Email: 15934846533@163.com）
Abstract：Firstly, the paper analyzed the pollution status of papermaking industry under environmental regulations. Secondly, the five indexes of industrial waste were selected to measure the intensity of environmental regulations in Chinas paper industry. Seven green technology innovation indicators were selected to carry out empirical analysis by gray correlation method. The results showed that there was the highest correlation between the intensity of environmental regulationsand the expenditure of new product development, and the correlation between the intensity of environmental regulations and R&D expenditure was the smallest, and the correlation degrees from low to high in between were the new product sales income, the number of new product development projects, the patent number applied and R&D personnel. And on this basis,the corresponding countermeasures for Chinas paper industry green development under the environmental regulations were put forward.
Key words：environmental regulation; paper industry; green technology innovation; countermeasures research
纸浆木聚糖酶生物助漂技术进展
陈阳雷1 吉兴香2,* 许 凤1,2,*
(1.北京林业大学林木生物质化学北京市重点实验室，北京，100083；
2.齐鲁工业大学制浆造纸科学与技术教育部/山东省重点实验室，山东济南，250353）
摘 要：生物技术在制浆造纸工业上的应用日益受到重视，尤其是半纤维素酶在纸浆漂白中的作用尤为突出。目前木聚糖酶生物辅助漂白已成为一项比较成熟的技术，并在制浆造纸工业中得到了广泛应用。本课题介绍了纸浆木聚糖酶生物助漂技术的进展，同时也阐述了木聚糖酶助漂的相关机理及其在工业应用中常用漂白程序和工艺参数。
关键词：纸浆；木聚糖酶；生物；漂白
中图分类号：TS745
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.013
Technical Progress in Xylanase Bio bleaching of Pulp
CHEN Yanglei1 JI Xingxiang2,* XU Feng1,2,*
(1. Beijing Key Lab of Lignocellulosic Chemistry, Beijing Forest University, Beijing, 100083;
2. Key Lab of Pulp & Paper Science and Technology of Ministry of Education/Shandong Province, Qilu University of Technology,
Jinan, Shandong Province, 250353)
(*Email: xxjt78@163.com; xfx315@bjfu.edu.cn)
Abstract：The application of biotechnology in pulp and papermaking industry has been obtained more and more attention, especially the role of hemicellulase in pulp bleaching. Now xylanase biobleaching has become a more reliable technology,and it has been widely used in the pulp and papermaking industry. The development of xylanase biobleaching technology of pulps was introduced in this paper, and the mechanism of xylanaseboosting bleaching, bleaching sequences and parameters commonly used in industry of xylanase were discussed.
Key words：pulp; xylanase； biology; bleaching
膜转移施胶系统在
高速箱纸板机上的应用
孙 浩 吕晓峰 徐清凉
（浙江景兴纸业有限公司，浙江嘉兴，314000）
摘 要：主要介绍了膜转移施胶系统在浙江景兴纸业有限公司高速箱纸板机上的应用。实践表明，通过添加淀粉胶并使用膜转移施胶系统，使生产的箱纸板的耐破指数、环压指数和耐折度分别提高了15.4%、33.8%和91.2%，且经济效益显著。
关键词：改造；淀粉制备系统；膜转移施胶机；箱纸板；经验
中图分类号：TS764.6;TS734+.8
文献标识码：A
DOI：10.11980/j.issn.0254508X.2017.12.014
Application of the Film Sizing Technology on High Speed Linerboard Machine
SUN Hao* LV Xiaofeng XU Qingliang
(Zhejiang King Hing Paper Co., Ltd., Jiaxing, Zhejiang Province, 314000)
(*Email: 1950771544@qq.com)
Abstract：In order to improve product quality and expand market share, Jing Xing paper uses film transfer sizing technology on PM12. The film transfer sizing machine and starch preparation system were supplied respectively by Valmet and GAW. Through the rebuilding, the mill not only improves the quality of linerboard, but also accumulate a lot of modification experience.
Key words：modification; starch preparation system; the film transfer sizing machine; linerboard; experience
《中国造纸》2017年总目次
(第36卷1～12期)
题 目 期 号 页 码
◆原料 备料
对位芳纶浆粕形态结构与性能研究曹雪鸿等2(18)
乙醇木素的提纯研究周立春等2(28)
麦草热水预水解过程产物分析及木糖生成模型马 浩等3(1)
巨菌草纤维特性分析及其木素结构表征沈 锋等3(13)
麦草酸水解提取木糖的探究马 浩等4(36)
三年生花眉竹不同部位纤维形态特征的分析研究李 权等6(21)
响应曲面法优化过氧甲酸提取竹子纤维素的工艺
研究吴德智等7(9)
杨木自水解过程中木素对木片颜色影响的研究张 鑫等7(14)
粉单竹竹青色素提取工艺及其成分分析金 叶等9(24)
槟榔壳原料及制浆性能研究邓 通等9(39)
木芙蓉皮成纸可行性研究王 珊9(43)
C3HRNAi转基因杨木木质部纤维形态特征研究苏明垒等12(21)
◆制浆及其设备
TEMPO氧化体系选择性氧化未漂非木浆的研究张德志等1(9)
纳米纤维素的制备及其复合材料的应用研究进展张思航等1(67)
肉桂酰化聚木糖改善APMP浆性能的研究周慧芳等2(1)
蒸汽爆破废纸稀酸水解的研究李奇明等3(7)
商品化学浆制备溶解浆的研究进展范述捷等3(64)
改性漆酶协同谷氨酸改善二次纤维微观结构及性能的
研究孔凡娇等4(1)
纸浆的超声波打浆成效于 群等4(25)
基于RSM模型对纤维素酶预处理制备MFC的参数
优化张启莲等7(1)
精筛断轴案例分析及轴类零件国产化探讨燕 盼7(54)
蒸煮管筒体爆炸事故分析周 波等7(58)
纳米微纤丝纤维素及其在造纸中的应用研究现状占正奉等7(70)
蔗渣碱抽提半纤维素及蒸煮的工艺研究李亚辉等9(6)
桉木硫酸盐法制浆黑液木素提取与表征李媛媛等10(18)
自水解对速生杨木片碱浸渍性能影响的研究江骁雅等11(1)
◆纸及纸板生产
提高证券纸耐折度的研究赵亚伦等2(6)
改性麻浆制备PM2.5口罩滤纸的研究胡潇雨等2(33)
纤维表面改性对纸基摩擦材料原纸强度性能的影响
胡文静等2(12)
纸基摩擦材料坯体组分的研究现状李坤鹏等2(53)
仿塑印刷纸生产技术探讨武建峰3(69)
一种具有保湿功能卷烟纸的研发余振华等4(42)
卷烟纸麻浆含量对卷烟感官质量的影响陈笃建等4(46)
酶转化淀粉在无碳复写纸原纸中的应用齐云洹等4(71)
基于Fluent的帘式涂布模头内流场数值模拟潘 岳等5(14)
纳米纤维素增强芳纶云母纸性能的研究党婉斌等5(21)
高档美纹纸层间剥离强度的研究左建波等5(30)
纸机湿部配置对安全线防伪纸质量的影响杨树忠5(41)
棉秆生物氧化机械浆生产本色擦手纸的实践滕铁生等5(72)
锌银电池隔膜纸的制备及性能研究李会丽等6(1)
负载TiO2陶瓷纤维与高得率浆混抄对纸张强度和
返黄性能的影响胡嘉驹等6(7)
卷烟纸特性对细支烟主流烟气指标的影响李海锋等6(38)
用圆网纸机生产高效真空吸尘器纸袋原纸的工艺
研究刘文波等7(20)
纤维型吸油材料的制备及其吸油性能的研究刘嘉佩等7(31)
微胶囊在卷烟用纸上的应用评价沈 妍等7(36)
卷烟纸对卷烟凝灰性能的影响分析张 莹等7(44)
草浆白泥碳酸钙加填时AKD施胶问题的研究现状
张亚增等7(79)
高清亮光数码喷墨相纸原纸的生产实践黄学英等7(84)
PET纤维直径对过滤纸结构和性能的影响郝青青等8(1)
麦草化学浆抄造轻型印刷纸的研究张 权等8(30)
帘式涂布幕帘稳定性影响因素研究李洪才等9(1)
棉浆纤维磷酸酯化及其对打浆性能的影响钱 丽等9(13)
采用湿法成形工艺制备聚烯烃碱性电池隔膜的研究
张丙旭等9(17)
电子元器件用纸质载带简介李双晓等9(74)
低引燃倾向卷烟纸的研究与应用郑 晗等9(78)
不同长径比PET纤维对纸基复合材料强度性能的
影响张素风等10(7)
液晶玻璃间隔纸抄造工艺的研究徐永建等10(13)
打浆工艺对造纸法再造烟叶基片松厚度的影响袁广翔等10(30)
纳米纤维素的疏水性及分散性研究进展杨 爽等10(61)
提高造纸法再造烟叶松厚度及吸收性能的策略李美灿等10(68)
冷冻干燥法制备纤维素基多孔材料的研究马珊珊等11(29)
钛白粉高岭土复合填料的制备及应用衣 然等11(37)
油浸绝缘纸制备技术及研究进展于红梅等11(57)
胶黏物模型物在抄造系统中的稳定特性研究耿胜芳等12(1)
机械木浆纤维形变性表征及其对纤维间结合性能的
影响王 欣等12(14)
不同溶剂预处理对烟梗打浆抄造及评吸性能的
影响侯 轶等12(39)
竹纤维真空绝热板芯材的结构和性能研究董 旭等12(45)
◆纸机及其辅助设备
纸巾纸机收放卷过程运动学分析及应用柳天磊1(52)
Sym ZS Roll系统在卷烟纸机上的应用刘 娜2(45)
伺服电子凸轮在切纸机切纸辊上的应用马文明等2(49)
纸机干燥部热力控制系统发展综述汤 伟等2(59)
面向对象方法在复卷机程序设计中的应用尚 苗等3(59)
矩形肋槽烘缸的导热模型师晋生等5(36)
从真空系统、刮刀及在线脱水测量协同角度探讨
纸机节能及系统优化杨凤辉6(59)
磨浆机的穿流磨浆模式及初步分析王 平等8(46)
带有蒸汽排出装置的高浓磨浆机磨片杨建伟等8(60)
基于CFD数值模拟的纸浆压力筛筛鼓棒条形状改进
分析荣学青等9(54)
盘磨机磨区内纸浆流动研究与进展刘 欢等9(66)
基于改进遗传算法的造纸机干燥部排风系统参数
优化汤 伟等10(44)
纸卷硬度计RoQ在造纸行业的应用钱 恩10(50)
靴压可控中高辊多油垫流体静力支承的应用研究
李若冰等10(57)
宽幅纸机液压刮刀摆动器的设计与开发李若冰12(63)
膜转移施胶系统在高速箱纸板机上的应用孙 浩等12(79)
◆废纸脱墨
废油脂制备表面活性剂及在浮选脱墨中的应用唐振等5(25)
MADAOS二元共聚物的制备及在浮选脱墨中的
应用游群杰等8(6)
◆洗涤 筛选 漂白
漂白助剂对蔗渣浆D0EpD1漂白的影响闫兆晴等4(7)
综合法二氧化氯制备中发生器工艺的对比李丽萍等6(64)
低浓亚麻浆臭氧漂白工艺的研究何 甜等10(1)
亚麻浆新型ZEMP漂白工艺研究何 甜等11(8)
洗漂过程对棉浆黏度影响因素的研究邹 杨等12(27)
纸浆木聚糖酶生物助漂技术进展陈阳雷等12(74)
◆湿部化学 化学品
不同方法制备的淀粉基生物胶乳的性能研究杜艳芬等1(1)
季戊四醇多聚磷酸酯三聚氰胺盐用作纸张阻燃剂的
研究黄高能等1(15)
纳米纤化纤维素接枝AMPS及其在高吸水树脂中的
应用研究温洋兵等3(21)
戊二醛接枝季铵型阳离子PVA与PAE协同作用对
纸张的增强范 丹等4(13)
阴离子树枝状聚酰胺胺在有机微粒助留助滤
体系中的应用秦 影等4(19)
酸化糟朽纸张增湿强研究张 娟等4(31)
催化纸催化材料的制备及固着方式的研究进展满孝兵等4(60)
植物纤维食品接触材料中邻苯二甲酸酯类增塑剂的
研究现状张 倩5(53)
阳离子淀粉改性硅藻土造纸填料的制备与表征尚 尉等6(17)
改性水凝胶包覆石膏晶须及在造纸过程中的溶出
抑制赵厚宽等6(32)
多功能复配液应用于纸质文物保护黄 杰等8(26)
沙蒿胶、瓜尔豆胶对纸质文物加固的初步研究吴依茜等12(32)
聚乙烯亚胺改性硅藻土的制备与表征尚 尉等12(51)
◆自动控制 传动控制
复卷机传动控制系统的设计及应用马晓宇1(57)
国产全自动造纸表面施胶淀粉连续制备系统杨能生等4(51)
基于AB平台的造纸机传动控制系统设计及应用马文明4(55)
基于PF753实现的复卷机传动控制系统及其应用赵 丹等5(48)
基于自适应变异差分进化算法的溶解氧浓度控制
系统汤 伟等6(49)
生活用纸工厂多仓库订单自动分单与调度优化
系统的研发王 波等6(55)
基于FNN解耦纸张定量水分控制策略的研究与
应用胡亚南等7(48)
改进遗传算法PID参数优化在流浆箱总压控制中的
应用莫卫林等8(35)
边缘跟踪算法在多纸病图像分割中的应用李 茜等8(41)
改进蚁群算法在盘磨进退刀控制中的应用李 茜等9(48)
基于ProfibusDP的4400/600纸机传动控制系统
设计及应用武 昆等9(60)
膜转移施胶机的电气控制王 睿10(54)
模糊PID在卫生纸机烘缸进出口差压控制中的
应用汤 伟等11(50)
◆废水处理 碱回收设备 环保综合利用
生物促生剂对废纸造纸活性污泥胞外聚合物的影响
张安龙等1(24)
造纸污泥表面改性的研究毛 杰等1(31)
磷酸活化脱墨渣制备中孔活性炭研究程富江等1(36)
葡萄糖浓度对微氧磁性活性污泥降解五氯酚的影响
兰善红等1(42)
厌氧预处理在蔗渣制浆废水好氧生化处理中的应用江耀春2(40)
聚多巴胺功能化的纤维素材料用于造纸废水中有机
染料的催化王艳薇3（26）
基于动力学和POSSVM的废水厌氧处理产气量的混合
软测量模型刘 林3（31）
制浆中段废水处理优势菌的鉴定及其对COD去除
效果的研究党亚攀3（37）
造纸白泥制备陶瓷滤料的技术研究顾敏佳等3(72)
悬浮填料生物膜MBR系统处理制浆中段废水的
研究管 鑫等5(1)
赖氨酸改性纳米纤维素的表征及其对亚甲基蓝的
吸附行为研究万小芳等5(7)
硫化铟纳米粒子的合成及其对碱性木素的可见光
催化降解作用陈 骏等6(13)
基于竹浆制浆废水的EGSB反应器启动及颗粒污泥
特性研究刘 春等6(26)
AFSMBBR组合工艺处理制浆废水中试试验研究敬双怡等7(25)
造纸废水处理过程微小故障检测方法研究王龄松等8(20)
压力苛化在竹浆厂的应用魏彐彬8(68)
高铁酸钾与聚合氯化铝铁对造纸综合废水的处理郭 准9(30)
逆流提取工艺中浆料浓度对黑液提取率的影响韦之敏等11(13)
高浓竹浆黑液高温动态黏弹性研究岳小鹏等11(19)
氧化改性木素磺酸钙的制备及其对水泥净浆的
影响贾陆军等11(24)
碱回收炉爆炸事故的分析彭 成等11(74)
细菌纤维素絮凝材料制备及其处理造纸废水性能
研究孙映宏等12(9)
◆分析检测
热裂解/固相微萃取气质法分析卷烟纸浆料的
热裂解物张国强等1(20)
盘磨机磨盘磨损检测技术的研究刘庆立等1(47)
卷烟纸及其七种原料和助剂裂解产物对比分析肖卫强等2(23)
不同纸张干热老化性能研究田周玲等3(42)
小尺寸纸样匀度测试方法研究刘谷红等3(48)
一种适用于出入境证件中传统水印的智能鉴别算法张 梅3(53)
光泽度对镀铝纸光谱预测模型的影响鲍 蓉等8(13)
使用扫描电镜电子能谱仪检验鉴别静电复印纸陈维娜等10(37)
生活用纸质量监控与异常分析方法的研究汪 涵等11(44)
基于自适应神经模糊推理系统的纸病二次辨识王亚波等12(56)
◆专题论坛
2015年世界造纸工业概况邝仕均1(62)
《中国造纸》2016年发表文章述评马 忻等2(67)
轻型纸印刷的图书书页发长问题的分析与对策张永洋等4(66)
浅析根本原因分析技术在制浆造纸企业的应用刘 磊5(58)
循环经济理念下的造纸产业集群发展路径探索李 炜等5(64)
我国造纸产业经济增长的影响因素与发展路径研究张 培5(68)
樟木挥发物对纸质档案耐久性的影响研究贾智慧等6(43)
纸类产品的生命周期评价陈 钢6(67)
我国造纸行业的基本现状及发展对策张学斌等6(74)
中国造纸协会关于造纸工业“十三五”发展的
意见中国造纸协会7(64)
造纸废水资源化和超低排放关键技术及应用王双飞8(51)
车间级MIS系统在造纸企业生产管理中的应用胡宇航8(65)
用实力谱写数字化未来——ABB AbilityTM
——访ABB过程工业业务单元全球负责人罗杰·贝利及
ABB过程工业业务单元中国及北亚区负责人
蒋海波常 青等8(73)
日本纸和纸板的生产和消费动向及发展方向
——2016年、2017年日本造纸业的课题和展望8(77)
全球造纸产业科技领域国际合作研究的文献计量
分析周在峰等9(34)
造纸企业温室气体排放核算及其应用李永智等10(24)
低碳视角下我国造纸产业国际竞争力实例分析王海刚等10(74)
福伊特：传承德国工匠精神 引领技术创新
——访福伊特造纸亚洲区总裁喻致兵先生郭彩云10(79)
我国纸浆贸易逆差研究许 华等11(63)
造纸厂的大数据管理和应用赵小玲等11(70)
环境规制对我国造纸行业绿色技术创新的影响
研究许 华等12(67)
◆其他
TAPPI JOURNAL 2016年第11期目次1(76)
《中国造纸》2016年度“金泉磨片杯”优秀论文
评选结果揭晓2（彩色中插）
TAPPI JOURNAL 2017年1月目次4（75）
TAPPI JOURNAL 2017年2月目次4（76）
TAPPI JOURNAL 2017年第3期目次5（76）
TAPPI JOURNAL 2017年第4期目次7(87)
TAPPI JOURNAL 2017年第5期目次7(88)
TAPPI JOURNAL 2017年第6期目次8(83)
TAPPI JOURNAL 2017年第7期目次9(82)
APPITA 2016年第1期中英文摘要9(83)
TAPPI JOURNAL 2017年第8期目次10(84)
TAPPI JOURNAL 2017年第9期目次11(78)
APPITA 2016年第2期中英文摘要11(79)
《中国造纸》2017年总目次12（82）
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